Product ID:MILFORCE COMPONENT A POLYMERIC MDI MFORCE-A
MSDS Date:11/01/1992
FSC:8040
NIIN:00N040174
Kit Part:Y
MSDS Number: BRPRQ

SEALED AIR CORP

OLD SHERMAN TNPK
DANBURY, CT 06810
US

Emergency Phone: 203-791-3500;800-424-9300(CHEMTREC)

Info Phone: 800-791-3500

Cage: 51614

SEALED AIR CORP INSTAPAK DIVISION

DANBURY, CT 06810 US

Telephone: 203-791-3500/800-424-9300(CHEMTREC)

Cage: 51614

WAS SEEN IN HIGHEST EXPOS GROUP (30 TIMES OSHA PEL)

RTECS: 9999999ZZ

BASED ON INFO, IT IS HIGHLY UNLIKELY THAT TUMOR FORM

RTECS: 9999999ZZ

CARTRIDGE TYPE RESPS EQUIPPED FOR ORG VAPS ARE

RTECS: 9999999ZZ

BE USED FOR SHORT TERM EMER SITUATIONS AT CONCS

RTECS: 9999999ZZ

ASSURED. WHERE CONCENTRATIONS EXCEED PEL,

RTECS: 9999999ZZ

ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (4,4'

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: 45%

OSHA PEL 0.02 PPM, C

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

POLYMETHYLENEPOLYPHENYL ISOCYANATE; (HIGHER MOLECULAR

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 45%

DURING SPILL CLEAN-UP AND VENTILATION

RTECS: 9999999ZZ

INGEST IS

RTECS: 9999999ZZ

STOM & DIGESTIVE TRACT.ONLY AT HIGHEST EXPOS,30 TIMES

RTECS: 9999999ZZ

OF BENIGN (NON-CANCEROUS) TUMORS & ONE MALIGNANT

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL,RAT): >20 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: MAY LEAD TO MUC MEMB IRRIT,
TIGHTENING OF CHEST, RESP TRACT IRRIT, COUGHING, HDCH, SHORTNESS OF
BRTH. MAY LEAD TO ALLERGIC SENSITIVITY IN SOME INDIV RSLTG IN
ASTHMA-LIKE SYMPS UPON EXPOS BELOW PEL.SENSITIZED PERSONS SHOULD
BE REMOVED FROM ANY FURTHER EXPOS. SKIN: MAY CAUSE IRRIT/RASH. CAN
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SKIN DISCOLORATION. RPTD CONT MAY
RSLT IN SKIN SENSIT. ANIMAL TESTS HAVE INDICATED THAT RESP SENSIT
CAN RSLT FROM SKIN CONT W/MDI. DATA REINFORCES NEED TO PVNT DIRECT
SKIN CONT. EYE: LIQ CAN CAUSE EYE IRRIT, TEARING, REDDENING &
SWELLING. PERM CORNEAL INJ IS UNLIKELY. ING ADDDN, VAPS IN EXCESS
OF 0.02 (ING 4)
Medical Cond Aggravated by Exposure:PULMONARY DISORDERS. PERSONS WITH
ASTHMA-TYPE CONDITIONS OR OTHER CHRONIC RESPIRATORY DISEASES SHOULD
BE EXCLUDED FROM WORKING WITH MDI.

First Aid:INHAL: REMOVE TO UNCONTAMD AREA, ADMIN OXYGEN IF NEC.
ASTHMA-LIKE SYMPS, IF MANIFESTED, MAY DEVELOP IMMED/BE DELAYED FOR
UP TO SEVERAL HRS. OBTAIN MED ATTN. TREATMENT IS SYMP. SKIN: WASH
AREA THORO W/ SOAP & WATER. LAUNDER CONTAMD CLTHG BEFORE REUSE.
EYE: FLUSH W/WATER FOR AT LST 15 MINS, HOLDING LIDS OPEN W/FINGERS.
CONSULT PHYS. INGEST: DO NOT INDUCE VOMIT. DRINK WATER TO REDUCE
CORR. (SUPDAT)

Flash Point Method:PMCC
Flash Point:390F,199C
Extinguishing Media:CARBON DIOXIDE, CHEMICAL FOAM, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROT
EQUIP . AVOID WATER CONTAM IN CLSD CNTNRS; CARBON DIOXIDE IS
EVOLVED WHICH CAN CAUSE PRESS BUILD-UP. (SUPDAT)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:SPILL SHOULD BE COVERED W/LOOSE, ABSORB,
NON-BIODEGRADABLE MATL. POUR DEACTIVATING SOLN (90% WATER, 8% CONC
AMMONIA, 2% DETERGENT) OVER SPILL AREA; ALLOW TO REACT 10
MINS/LONGER. COLLECT MATL IN OPEN CNTNRS & TREAT W/ADDNL
DEACTIVATING SOLN; (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORAGE TEMPERATURE: MIN. 50F (10C)
MAX 100F (38C). AVERAGE SHELF LIFE: 6 MONTHS. DO NOT STORE DRUMS
UNCOVERED OUT OF DOORS.
Other Precautions:DO NOT RESEAL CONTAINERS UNLESS IT IS CERTAIN THAT NO
MOISTURE CONTAMINATION HAS OCCURED. DO NOT BREATH VAPORS OR ALLOW
SKIN CONTACT.

Respiratory Protection:DUE TO LOW VAP PRESS OF MATL,PEL IS NOT LIKELY
TO BE EXCEEDED UNDER NORM CNDTNS.IF MATL IS HEATED OR SPILLED IN
CONFINED AREA,RESP PROT SHOULD BE WORN.BECAUSE OF THEIR SHORT LIFE
& LACK OF BREAKTHROUG H INDICATORS, NIOSH/MSHA APPRVD (ING 9)
Ventilation:USE LOCAL EXHAUST IF NECESSARY TO MAINTAIN LEVELS BELOW
PEL.
Protective Gloves:BUTYL RUBB, NITRILE RUBB/PVC GLOVES.
Eye Protection:CHEM WORK GOG/FULL LGTH FACESHLD .
Other Protective Equipment:SAFETY SHOWER, EYEWASH STATION &
DEACTIVATING SOLN SHOULD BE AVAIL. SEE "RECOM FOR SAFE USE & HNDLG
OF INSTAPAK (SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: CAUTION: RXN BETWEEN WATER & HOT ISOCYANATE CAN BE
VIGOROUS. FIRST AID PROC: CONSULT PHYS. TREATMENT IS SYMP. OTHER
PROT EQUIP: FOAM-IN-PLACE CHEMS" BULLETIN BEFORE OPER EQUIP. SPILL
PROC: ALLOW TO STAND UNCOVERED FOR 48-72 HRS. WASH AREA
W/DEACTIVATING SOLN. RESP, EYE & SKIN PROT SHOULD BE WORN(ING 3)

Boiling Pt:B.P. Text:625F,329C
Vapor Pres:ING 1
Vapor Density:8.5
Spec Gravity:1.24 @ 25C
Solubility in Water:REACTS WITH WATER
Appearance and Odor:DARK BROWN LIQUID, SLIGHTLY AROMATIC ODOR.
Percent Volatiles by Volume:NIL

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, SURFACE ACTIVE MATERIALS.
Stability Condition to Avoid:TEMPERATURES ABOVE 110F (43C) OR BELOW 40F
(4C), CONTACT WITH MOISTURE AND OTHER MATLS WHICH CONTAIN ACTIVE
HYDROGEN.
Hazardous Decomposition Products:BY FIRE OR EXTREME HEAT, OXIDES OF
CARBON, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:ELEVATED TEMPERATURES.

Waste Disposal Methods:INCINERATE OR DISPOSE OF IN ACCORDANCE WITH
EXISTING FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL
REGULATIONS. ALSO SEE "RECOMMENDATIONS FOR SAFE USE AND HANDLING OF
INSTAPAK FOAM-IN-PLACE CHEMICALS " BULLETIN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.